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4.Customs Synthesis

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Product Name: Turpentine oil
Synonyms: TURPENTINE SUBSTITUTE;TURPENTINE OIL;Turpentine oil - rectified;PURIFIED GUM SPIRITS;OIL OF TURPENTINE (RECTIFIED);OIL OF TURPENTINE;THUS GUM;L-TURPENTINE
CAS: 8006-64-2
MF: C12H20O7
MW: 276.283
EINECS: 232-350-7
Product Categories: INORGANIC & ORGANIC CHEMICALS;Cosmetic Ingredients & Chemicals;Plant extracts;Herb extract;Essential oil
Mol File: 8006-64-2.mol
Turpentine oil Structure
Turpentine oil Chemical Properties
mp  −55 °C(lit.)
bp  153-175 °C(lit.)
density  0.86 g/mL at 25 °C(lit.)
vapor density  4.84 (−7 °C, vs air)
vapor pressure  4 mm Hg ( −6.7 °C)
FEMA  3089
refractive index  n20/D 1.515
Fp  86 °F
Stability: Stable. Flammable. Incompatible with chlorine, strong oxidizers.
Safety Information
Hazard Codes  Xn,N
Risk Statements  36/38-43-65-51/53-20/21/22-10
Safety Statements  36/37-46-61-62
RIDADR  UN 1299 3/PG 3
WGK Germany  2
RTECS  YO8400000
HazardClass  3.2
PackingGroup  III
Hazardous Substances Data 8006-64-2(Hazardous Substances Data)
MSDS Information
Provider Language
Turpentine oil English
SigmaAldrich English
Turpentine oil Usage And Synthesis
Chemical Properties colourless liquid with paint-like odour
General Description A clear colorless liquid with a characteristic odor. Flash point 90-115°F. Obtained from naphtha-extraction of pine stumps. Less dense than water and insoluble in water. Hence floats on water. Vapors are heavier than air.
Air & Water Reactions Highly flammable. Insoluble in water.
Reactivity Profile WOOD TURPENTINE reacts with oxidizing agents. Calcium hypochlorite was placed in a turpentine container, thought to be empty. Reaction with the residual turpentine resulted in an explosion within a few minutes [Benson 1967]. Reacts violently with chromic anhydride [Haz. Chem. Data 1967 p. 68]. Reacts with stannic chloride producing heat and sometimes flame [Mellor 7:430 1946-47]. May also react exothermically with reducing agents to produce gaseous hydrogen.
Turpentine oil Preparation Products And Raw materials
Preparation Products Rosin-->Iron oxide red phenolic antirust paint-->Linalool-->Phenolic resin paint-->Camphor-->Cinene-->TERPINEOL-->DL-Isoborneol-->(-)-alpha-Terpineol-->TOXAPHENE-->Pine oil-->Camphene-->Isobornyl acetate-->Terpinyl acetate-->Penetrating agent 5881D-->2-ETHYLBUTYL METHACRYLATE-->alpha-Pinene-->4-Allylanisole-->ALPHA-TERPINENE-->Borneol -->beta-Pinene -->Dihydromyrcene-->ABIETIC ACID-->Bornyl acetate-->L(-)-Borneol