- Product Details
Keywords
- Potassium hydrogen fluoride
- 7789-29-9
- F2HK
Quick Details
- ProName: F2HK Potassium hydrogen fluoride 778...
- CasNo: 7789-29-9
- Molecular Formula: F2HK
- Appearance: Powder
- Application: 7789-29-9 ...
- DeliveryTime: by air
- PackAge: Aluminium Foil Bag and Paper Drum
- Port: Any port of China
- ProductionCapacity: 100 Metric Ton/Day
- Purity: 99.5%
- Storage: 1MT
- Transportation: By Sea/Air/DHL
- LimitNum: 1 Metric Ton
- Grade: Industrial Grade,Food Grade,Pharma Gra...
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Details
Potassium hydrogen fluoride Basic information |
Product Name: | Potassium hydrogen fluoride |
Synonyms: | Bifluorure de potassium;bifluoruredepotassium;Hydrogen potassium fluoride;hydrogenpotassiumfluoride;K(HF2);NA 1811;Potassium acid fluoride;Potassium fluoride (K(HF2)) |
CAS: | 7789-29-9 |
MF: | F2HK |
MW: | 78.1 |
EINECS: | 232-156-2 |
Product Categories: | Inorganic Chemicals;Inorganics;C-X Bond Formation (Halogen);Fluorination;Synthetic Reagents;metal halide;Fluorination Reagents;Chemical Synthesis;Synthetic Reagents |
Mol File: | 7789-29-9.mol |
Potassium hydrogen fluoride Chemical Properties |
Melting point | 239 °C(lit.) |
density | 2.37 g/mL at 25 °C(lit.) |
form | Crystals or Crystalline Powder |
color | White to light gray |
Water Solubility | 39 g/100 mL (20 ºC) |
Sensitive | Hygroscopic |
Merck | 14,7610 |
CAS DataBase Reference | 7789-29-9(CAS DataBase Reference) |
NIST Chemistry Reference | Potassium hydrogen fluoride(7789-29-9) |
EPA Substance Registry System | Potassium fluoride (K(HF2))(7789-29-9) |
Safety Information |
Hazard Codes | T,C |
Risk Statements | 25-34 |
Safety Statements | 26-36/37/39-45-37-22 |
RIDADR | UN 3421 8/PG 2 |
WGK Germany | 1 |
RTECS | TS6650000 |
F | 3 |
Hazard Note | Corrosive |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | II |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Potassium hydrogen fluoride Usage And Synthesis |
Description | Potassium hydrogen fluoride is used as an etchant to etch glass surface and it is used in the cleaning products. It is used as a fluorinating agent for fluorinated organic compounds, which could be applied as finishing agent for fabrics, components of extinguishing agents, electroplating bathes, lubricating oils, oxygen carriers in blood substitutes. For example, potassium hydrogen fluoride is used as fluorinating agent for ring opening of epoxides and cyclopropanes and in the synthesis of trifluoroborates from various organoborons. It may also serve as a fluoride ion source for the nucleophilic ring-opening reaction of epoxide. |
References |
[1] Gary A. Molander, David J. Cooper and Stephen W. Wright, Potassium Hydrogen Fluoride, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001 [2] Bernd Basner, Houben-Weyl Methods of Organic Chemistry Vol. E 10b/1, 4th Edition, 1999 [3] Francis I. Onuska and Francis W. Karasek, Open Tubular Column Gas Chromatography in Environmental Sciences, 1984 [4] Michael Howe, Wheel cleaning composition containing acid fluoride salts, Patent “US 5556833 A”, 1996 [5] Grzegorz Lewandowski, Egbert Meissner and Eugeniusz Milchert, Special applications of fluorinated organic compounds, Journal of Hazardous Materials, 2006, vol. 136, 385-391 |
Chemical Properties | WHITE TO LIGHT GREY CRYSTALS OR CRYSTALLINE POWDER |
Uses | In the preparation of pure potassium fluoride; as an electrolyte in the manufacture of fluorine; frosting glass; treating coal to prevent slag formation; flux for silver solders; catalyst in the alkylation of benzene with olefins. |
General Description | Colorless crystals, corrosive to tissues, etches glass. |
Air & Water Reactions | Water soluble giving strongly acidic solutions. |
Reactivity Profile | Acidic salts, such as Potassium hydrogen fluoride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. |
Health Hazard | TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. |
Fire Hazard | Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. |
Potassium hydrogen fluoride Preparation Products And Raw materials |